I also liked the book, although let me point out that this is a "mass market" text, and this give nothing but the broadest overview of Mr. Taleb's trading strategy. I don't know if it was necessarily supposed to impart particular financial knowledge. Rather, it's just a very long essay series on the ways people tend to misjudge probabilities, risk and reward. The discussions he gives of the financial world mostly seem like anecdotes he gives to prove a point. As such, it is half-math, half-psychology. It's actually fairly "light" reading, and very enjoyable at that. So I really quite recommend it.
I think he may rub some people in the finance world the wrong way by claiming that most successful traders are lucky rather than good and claiming that people who follow day-to-day movement of stock indices are wasting their time. But as I come from an engineering background rather than a finance background, that doesn't offend me at all ;-)
As far as some of the criticism that his investment strategy commits the same crime as what he criticizes others for, that would seem at the surface to be true, and this is a point worth investigating. As he describes it, his strategy seems like a simple arbitrage play - make investments that pay off big in the case of unexpected events - because people undervalue the probability of these events. And one would think that over time, like any other arbitrage strategy, it would start to lose usefulness. That is, if it works for him, then other people will recognize that, the market will correct the prices, and there will no longer be an arbitrage opportunity. However, as I understand it, based on the other points he makes in the book, he's betting this won't happen. Why? Because any trader following this strategy will compile a steady stream of losses, with an occasional big payout. Because of the way humans experience risk and reward, actually carrying out such a trading strategy is psychologically very difficult. (And maybe even more difficult to justify to your backers.)
Whether this is true or not I don't know. Without evidence of how his fund is doing, I suspect your opinion on this has more to do with one's beliefs in efficient markets and the like than anything else.
Joe